²⁹Si MAS data

Experiment performed with 4-mm diameter rotor spinning at 10 kHz. δ_CS = +1.45 ppm.

Acquisition parameters:

²⁹Si MAS T2 echo data

The ²⁹Si echo train is obtained with cpcpmg.fau pulse sequence.

²⁹Si MAS T1 data

The ²⁹Si T1 data is obtained with the inversion-recovery T1ir pulse program;
NS = 4 and D1 = 180 s.

¹H MAS data

Experiment performed with 4-mm diameter rotor spinning at 10 kHz.

Acquisition parameters:

Reference

1. Shigenobu Hayashi and Kikuko Hayamizu
   Chemical shift standards in high-resolution solid-state NMR (1) ¹³C, ²⁹Si, and ¹H nuclei,
   Bull. Chem. Soc. Jpn. 64, 685-687 (1991).
   Open Access
2. Shigenobu Hayashi and Kikuko Hayamizu
   Chemical shift standards in high-resolution solid-state NMR (2) ¹⁵N nuclei,
   Bull. Chem. Soc. Jpn. 64, 688-690 (1991).
   Open Access
3. Søren L. Poulsen, Vanessa Kocaba, Gwenn Le Saoüt, Hans J.Jakobsen, Karen L. Scrivener, and Jøgen Skibsted
   Improved quantification of alite and belite in anhydrous Portland cements by ²⁹Si MAS NMR: Effects of paramagnetic ions,
   Solid State Nucl. Magn. Reson. 36, 32-44 (2009).
   Abstract