Indium-113 and indium-115 NMR

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Isotope Spin Natural
abundance (%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
In-113 9/2 4.28 79.9 0.34 1.47E-2 -21.866 In(NO3)3
In-115 9/2 95.72 81.0 0.34 0.33 -21.914

Solid-state indium NMR references

  1. Andrii Mahun, Sabina Abbrent, Jiri Czernek, Jan Rohlicek, Hana Macková, Weihua Ning, Rafał Konefał, Jiří Brus, and Libor Kobera
    Reconstructing reliable powder patterns from spikelets (Q)CPMG NMR spectra: Simplification of UWNMR crystallography analysis,
    Molecules 26, 6051/1-6051/13 (2021).
    Open access
  2. Kent J. Griffith, Fenghua Ding, and Steven Flynn
    Solid-state nuclear magnetic resonance of spin-9/2 nuclei 115In and 209Bi in functional inorganic complex oxides,
    Magn. Reson. Chem. 59, 1077-1088 (2021).
    Abstract
  3. Abhoy Karmakar, Guy M. Bernard, Alkiviathes Meldrum, Anton O. Oliynyk, and Vladimir K. Michaelis
    Tailorable indirect to direct band-gap double Perovskites with bright white-light emission: decoding chemical structure using solid-state NMR,
    J. Am. Chem. Soc. 142, 10780-10793 (2020).
    Abstract
  4. P. J. Knijn, P. J. M. van Bentum, C. M. Fang, G. J. Bauhuis, G. A. de Wijs, and A. P. M. Kentgens
    A multi-nuclear magnetic resonance and density functional theory investigation of epitaxially grown InGaP2,
    Phys. Chem. Chem. Phys. 18, 21296-21304 (2016).
    Abstract
  5. Hiyam Hamaed, Karen E. Johnston, Benjamin F. T. Cooper, Victor V. Terskikh, Eric Ye, Charles L. B. Macdonald, Donna C. Arnold, and Robert W. Schurko
    A 115In solid-state NMR study of low oxidation-state indium complexes,
    Chem. Sci. 5, 982-995 (2013).
    Abstract
  6. Fu Chen, Guibin Ma, Guy M. Bernard, Ronald G. Cavell, Robert McDonald, Michael J. Ferguson, and Roderick E. Wasylishen
    Solid-state 115In and 31P NMR studies of triarylphosphine indium trihalide adducts,
    J. Am. Chem. Soc. 132, 5479-5493 (2010).
    Abstract
  7. A. Y. H. Lo, T. Jurca, D. S. Richeson, and D. L. Bryce
    Multinuclear solid-state magnetic resonance study of In+ and Ag+ in neutral weakly coordinating environments,
    J. Phys. Chem. Lett. 1, 3078-3084 (2010).
    Abstract
  8. R. P. Chapman and D. L. Bryce
    Application of multinuclear magnetic resonance and gauge-including projector-augmented wave calculations to the study of solid group 13 chlorides,
    Phys. Chem. Chem. Phys. 11, 6987-6998 (2009).
    Abstract
  9. Fu Chen, Guibin Ma, Ronald G. Cavell, Victor V. Terskikhb, and Roderick E. Wasylishen
    Solid-state 115In NMR study of indium coordination complexes,
    Chem. Commun. 5933-5935 (2008).
    Abstract
  10. W. S. Jung, O. H. Han, and S. A. Chae
    Characterization of wurtzite indium nitride synthesized from indium oxide by In-115 MAS NMR spectroscopy,
    Mater. Lett. 61, 3413-3415 (2007).
  11. A. Goto, S. Ohki, K. Hashi, and T. Shimizu
    Optical-pumping double-resonance NMR system for semiconductors,
    Rev. Sci. Instr 77, 93904/1-93904/5 (2006).
  12. K. Yamada, K. Kumano, and T. Okuda
    Lithium superionic conductors Li3InBr6 and LiInBr4 studied by 7Li, 115In NMR,
    Solid State Ionics 177, 1691-1695 (2006).
  13. K. Yamada, K. Kumano, and T. Okuda
    Conduction path of the sodium ion in Na3InCl6 studied by X-ray diffraction 23Na and and 115In NMR,
    Solid State Ionics 176, 823-829 (2005).
  14. Y. Tomita, H. Matsushita, H. Yonekura, Y. Yamauchi, K. Yamada, and K. Kobayashi
    Li ion conductivity of solid electrolyte, Li3-2xMxInBr6 (M = Mg, Ca, Sr, Ba),
    Solid State Ionics 174, 35-39 (2004).
  15. T. J. Bastow and G. W. West
    Defects and hyperfine interactions in Ni-Y intermetallics (Y = Al, Ga, In, Ti) via 27Al, 47Ti, 61Ni, 69,67Ga and 115In nuclear resonance,
    J. Phys.: Condens. Matter 15, 8389-8406 (2003).
  16. P. E. Stallwortha, J.-F. Guillemoles, J. Flowers, J. Vedel, and S. G. Greenbaum
    NMR studies of CuInS2 and CuInSe2 crystals grown by the Bridgman method,
    Solid State Commun. 113, 527-532 (2000).
    Abstract
  17. M. Chatterjee, D. Bhattcharya, H. Hayashi, T. Ebina, Y. Onodera, T. Nagase, S. Sivasanker, and T. Iwasaki
    Hydrothermal synthesis and characterization of indium containing beta zeolite,
    Microporous Mesoporous Mater. 20, 87-91 (1998).
  18. A. Breuer and D. Siebert
    69Ga NMR and 115In NMR in AB2X4 crystals,
    Ber. Bunsenges. Phys. Chem. 100, 1736-1739 (1996).
  19. B. G. M. Chew, J. H. Golden, B. A. Huggins, F. J. DiSalvo, and D. B. Zax
    Probing the electronic structure in M2Mo6Se6: quadrupole couplings measured by NMR,
    Phys. Rev. B 50, 7966-7976 (1994).
  20. Oc Hee Han, Hye Kyung C. Timken, and E. Oldfield
    Solid-state "magic-angle" sample-spinning nuclear magnetic resonance spectroscopic study of group III-V (13-15) semiconductors,
    J. Chem. Phys. 89, 6046-6052 (1988).
  21. W. C. Bailey and H. S. Story
    Nuclear quadrupole coupling of 115In in NH4In(SO4)2·12H2O,
    J. Chem. Phys. 58, 1255-1256 (1973).

Related bibliography

  1. T. Iijima, K. Hashi, A. Goto, T. Shimizu, and S. Ohki
    Anisotropic indirect nuclear spin-spin coupling in InP: 31P CPNMR study under slow MAS condition,
    Chem. Phys. Lett. 419, 28-32 (2006).
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