Rubidium-85 and rubidium-87 NMR
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Isotope Spin Natural
abundance (%)		 Quadrupole moment
(10-30m2)		 Relative
sensitivity		 Absolute
sensitivity		 NMR frequency (MHz)
at a field of 2.3488T		 Reference
sample
Rb-85 5/2 72.15 27.6 1.05E-2 7.57E-3 -9.655 RbCl
Rb-87 3/2 27.85 13.35 0.17 4.87E-2 -32.721

Directory of solid-state Rb-85 and Rb-87 NMR references
Single Crystal Crystalline Powder
Rb2CrO4, RbVO3, Salt 		Amorphous Powder

Solid-state rubidium NMR references

  1. Tamar Wolf, Michael J. Jaroszewicz, and Lucio Frydman
    Quadrupolar isotope-correlation spectroscopy in solid-state NMR,
    J. Phys. Chem. C 126, 9386–9395 (2022).
    Open access
  2. Gang Wu, Victor V. Terskikh, and Alan Wong
    Perspectives of fast magic-angle spinning 87Rb NMR of organic solids at high magnetic fields,
    Magn. Reson. Chem. 59, 161-171 (2021).
    Abstract
  3. Henri Colaux, Daniel M. Dawson, and Sharon E. Ashbrook
    Investigating FAM-N pulses for signal enhancement in MQMAS NMR of quadrupolar nuclei,
    Solid State Nucl. Magn. Reson. 84, 89-102 (2017).
    Open access
  4. J. Schneider, J. Tsuchida, and H. Eckert
    Cation size effects in mixed-ion metaphosphate glasses: structural characterization by multinuclear solid state NMR spectroscopy,
    Phys. Chem. Chem. Phys. 15, 14328-14339 (2013).
    Abstract
  5. Thorsten Goebel, Alim Ormeci, Oliver Pecher, and Frank Haarmann
    The silicides M4Si4 with M = Na, K, Rb, Cs, and Ba2Si4 – NMR spectroscopy and quantum mechanical calculations,
    Z. Anorg. Allg. Chem. 638, 1437-1445 (2012).
    Abstract
  6. Thorsten Goebel, Yurii Prots, Alim Ormeci, Oliver Pecher, and Frank Haarmann
    Synthesis, crystal structure and chemical bonding of the Zintl phase Rb7NaSi8,
    Z. Anorg. Allg. Chem. 637, 1982-1991 (2011).
    Abstract
  7. L. A. O'Dell, K. J. Harris, and R. W. Schurko
    Optimized excitation pulses for the acquisition of static NMR powder patterns from half-integer quadrupolar nuclei,
    J. Magn. Reson. 203, 156-166 (2010).
    Abstract
  8. Nicole M. Trease, Krishna K. Dey, and Philip J. Grandinetti
    Optimum excitation of "enhanced" central transition populations,
    J. Magn. Reson. 200, 334-339 (2009).
    Abstract
  9. Ivan Hung, Alan Wong, Andy P. Howes, Tiit Anupõld, Ago Samoson, Mark E. Smith, Diane Holland, Steven P. Brown, and Ray Dupree
    Separation of isotropic chemical and second-order quadrupolar shifts by multiple-quantum double rotation NMR,
    J. Magn. Reson. 197, 229-236 (2009).
    Abstract
  10. Yannick Millot, Redouane Hajjar, and Pascal P. Mana
    Determination of NMR cogwheel phase cycle with XML,
    Solid State Nucl. Magn. Reson. 35, 223-239 (2009).
    Abstract
  11. Krishna K. Dey, Jason T. Ash, Nicole M. Trease, and Philip J. Grandinetti
    Trading sensitivity for information: Carr–Purcell–Meiboom–Gill acquisition in solid-state NMR,
    J. Chem. Phys. 133, 054501/1-054501/10 (2008).
    Abstract
  12. Joel A. Tang, Luke A. O’Dell, Pedro M. Aguiar, Bryan E. G. Lucier, Dimitris Sakellariou, and Robert W. Schurko
    Application of static microcoils and WURST pulses for solid-state ultra-wideline NMR spectroscopy of quadrupolar nuclei ,
    Chem. Phys. Lett. 466, 227-234 (2008).
    Abstract
  13. Luke A. O’Dell and Robert W. Schurko
    QCPMG using adiabatic pulses for faster acquisition of ultra-wideline NMR spectra,
    Chem. Phys. Lett. 464, 97-102 (2008).
    Abstract
  14. M. J. Thrippleton, T. J. Ball, and S. Wimperis
    Satellite transitions acquired in real time by magic angle spinning (STARTMAS): "Ultrafast" high-resolution MAS NMR spectroscopy of spin I = 3/2 nuclei ,
    J. Chem. Phys. 128, 34507/1-34507/9 (2008).
  15. Krishna K. Dey, S. Prasad, Jason T. Ash, Michael Deschamps, and Philip J. Grandinetti
    Spectral editing in solid-state MAS NMR of quadrupolar nuclei using selective satellite inversion,
    J. Magn. Reson. 185, 326-330 (2007).
    Abstract
  16. R. Bhattacharyya and L. Frydman
    Quadrupolar nuclear magnetic resonance spectroscopy in solids using frequency-swept echoing pulses,
    J. Chem. Phys. 127, 194503/1-194503/8 (2007).
  17. Vladimir K. Michaelis, Pedro M. Aguiar, and Scott Kroeker
    Probing alkali coordination environments in alkali borate glasses by multinuclear magnetic resonance,
    J. Non-Cryst. Solids 353, 2582-2590 (2007).
  18. T. J. Ball and S. Wimperis
    Use of SPAM and FAM pulses in high-resolution MAS NMR spectroscopy of quadrupolar nuclei,
    J. Magn. Reson. 187, 343-351 (2007).
  19. J. Trebosc, J.-P. Amoureux, and Z. H. Gan
    Comparison of high-resolution solid-state NMR MQMAS and STMAS methods for half-integer quadrupolar nuclei,
    Solid State Nucl. Magn. Reson. 31, 1-9 (2007).
  20. R. Siegel, T. T. Nakashima, and R. E. Wasylishen
    Sensitivity enhancement of NMR spectra of half-integer spin quadrupolar nuclei in solids using hyperbolic secant pulses,
    J. Magn. Reson. 184, 85-100 (2007).
  21. T. Vosegaard, C. Kehlet, N. Khaneja, S. J. Glaser, and N. C. Nielsen
    Improved excitation schemes for multiple-quantum magic-angle spinning for quadrupolar nuclei designed using optimal control theory,
    J. Am. Chem. Soc. 127, 13768-13769 (2005).
  22. S. E. Ashbrook and S. Wimperis
    Rotor-synchronized acquisition of quadrupolar satellite-transition NMR spectra: practical aspects and double-quantum filtration,
    J. Magn. Reson. 177, 44-55 (2005).
  23. N. Malicki, L. Mafra, A.-A. Quoineaud, J. Rocha, F. Thibault-Starzyk, and C. Fernandez
    Multiplex MQMAS NMR of quadrupolar nuclei,
    Solid State Nucl. Magn. Reson. 28, 13-21 (2005).
  24. J.-P. Amoureux, L. Delevoye, G. Fink, F. Taulelle, A. Flambard, and L. Montagne
    Implementing SPAM into STMAS: a net sensitivity improvement in high-resolution NMR of quadrupolar nuclei,
    J. Magn. Reson. 175, 285-299 (2005).
  25. B. O. Skadtchenko, M. Trudeau, R. W. Schurko, A. Y. H. Lo, and D. M. Antonelli
    Electronic properties and solid-state 87Rb and 13C NMR studies of mesoporous tantalum oxide rubidium fulleride composites,
    Chem. Mater. 17, 1467-1478 (2005).
  26. Renée Siegel, T. T. Nakashima, and R. E. Wasylishen
    Sensitivity enhancement of MQMAS NMR spectra of spin 3/2 nuclei using hyperbolic secant pulses,
    Chem. Phys. Lett. 403, 353-358 (2005).
  27. Christophe Odin
    Evidence of a phase transition of RbHCO3 from high-resolution solid-state 13C and 87Rb NMR by comparison with KHCO3,
    Magn. Reson. Chem. 42, 381-388 (2004).
    Abstract
  28. R. Siegel, T. T. Nakashima, and R. E. Wasylishen
    Signal enhancement of NMR spectra of half-integer quadrupolar nuclei in solids using hyperbolic secant pulses,
    Chem. Phys. Lett. 388, 441-445 (2004).
  29. R. W. Schurko, I. Hung, and C. M. Widdifield
    Signal enhancement in NMR spectra of half-integer quadrupolar nuclei via DFS-QCPMG and RAPT-QCPMG pulse sequences,
    Chem. Phys. Lett. 379, 1-10 (2003).
  30. H. T. Kwak and Z. H. Gan
    Double-quantum filtered STMAS,
    J. Magn. Reson. 164, 369-372 (2003).
  31. S. E. Ashbrook and S. Wimperis
    SCAM-STMAS: satellite-transition MAS NMR of quadrupolar nuclei with self-compensation for magic-angle misset,
    J. Magn. Reson. 162, 402-416 (2003).
  32. J.-P. Amoureux, C. Morais, J. Trebosc, J. Rocha, and C. Fernandez
    I-STMAS, a new high-resolution solid-state NMR method for half-integer quadrupolar nuclei,
    Solid State Nucl. Magn. Reson. 23, 213-223 (2003).
  33. P. K. Madhu, K. J. Pike, R. Dupree, M. H. Levitt, and M. E. Smith
    Modulation-aided signal enhancement in the magic angle spinning NMR of spin-5/2 nuclei,
    Chem. Phys. Lett. 367, 150-156 (2003).
  34. A. Jerschow and R. Kumar
    Calculation of coherence pathway selection and cogwheel cycles,
    J. Magn. Reson. 160, 59-64 (2003).
  35. R. Lefort, J. W. Wiench, M. Pruski, and J.-P. Amoureux
    Optimization of data acquisition and processing in Carr-Purcel-Meiboom-Gill MQMAS NMR,
    J. Chem. Phys. 116, 2493-2501 (2002).
  36. S. Wi, J. W. Logan, D. Sakellariou, J. D. Walls, and A. Pines
    Rotary resonance recoupling for half-integer quadrupolar nuclei in solid-state nuclear magnetic resonance spectroscopy,
    J. Chem. Phys. 117, 7024-7033 (2002).
  37. S. E. Ashbrook and S. Wimperis
    Satellite-transition MAS NMR of spin I = 3/2, 5/2, 7/2, and 9/2 nuclei: sensitivity, resolution, and practical implementation,
    J. Magn. Reson. 156, 269-281 (2002).
  38. D. D. Laws, H.-M. L. Bitter, and A. Jerschow
    Solid-state NMR spectroscopic methods in chemistry,
    Angew. Chem. Int. Ed. 41, 3096-3129 (2002).
  39. D. Massiot, F. Fayon, M. Capron, I. King, S. Le Calvé, B. Alonso, J.-O. Durand, B. Bujoli, Z. Gan, and G. Hoatson
    Modelling one- and two-dimensional solid-state NMR spectra,
    Magn. Reson. Chem. 40, 70-76 (2002).
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