Lithium-7 NMR references

Isotope	Spin	Natural abundance (%)	Quadrupole moment (10^-30m²)	Relative sensitivity	Absolute sensitivity	NMR frequency (MHz) at a field of 2.3488T	Reference sample
Li-6	1	7.42	-0.0808	8.50E-3	6.31E-4	-14.716	LiCl
Li-7	3/2	92.58	-4.01	0.29	0.27	-38.863

Directory of solid-state Li-6 and lithium-7 NMR references
Single Crystal	Crystalline Powder Oxide, Zeolite	Amorphous Powder

Solid-state lithium NMR references

Stephen Wimperis, George E. Rudman, and Karen E. Johnston
Biexponential I = 3/2 spin−lattice relaxation in the solid state: multiple-quantum ⁷Li NMR as a probe of fast ion dynamics,
J. Phys. Chem. C 128, 5453-5460 (2024).
Open access
Kikuko Hayamizu, Tomoyuki Haishi, Yasuhiko Terada, Kunimitsu Kataoka, and Junji Akimoto
⁷Li diffusion in thin disks of single-crystal garnet LLZO-Ta studied by PFG-NMR spectroscopy,
Recent Prog. Mater. 5 (2023).
Open access
Marie Duffiet , Maxime Blangero, Pierre Etienne Cabelguen, Kyeong Se Song, François Fauth, Claude Delmas, and Dany Carlier
Probing Al distribution in LiCo_0.96Al_0.04O₂ materials using ⁷Li, ²⁷Al, and ⁵⁹Co MAS NMR combined with synchrotron X-ray diffraction,
Inorg. Chem. 59, 2890-2899 (2020).
Abstract
W. M. J. Franssen, E. S. Blaakmeer, and A. P. M. Kentgens
Satellite nutation of half integer quadrupolar nuclei: Theory and practice,
J. Magn. Reson. 300, 41-50 (2019).
Open access
Cornelia Schröder, Jinjun Ren, Ana Candida M. Rodrigues, and Hellmut Eckert
Glass-to-crystal transition in Li_1+xAl_xGe_2−x(PO₄)₃: Structural aspects studied by solid state NMR,
J. Phys. Chem. C 118, 9400-9411 (2014).
Abstract
Michal Leskes, Amy J. Moore, Gillian R. Goward, and Clare P. Grey
Monitoring the electrochemical processes in the lithium-air battery by solid state NMR spectroscopy,
J. Phys. Chem. C 117, 26929-26939 (2013).
Abstract
J. Schneider, J. Tsuchida, and H. Eckert
Cation size effects in mixed-ion metaphosphate glasses: structural characterization by multinuclear solid state NMR spectroscopy,
Phys. Chem. Chem. Phys. 15, 14328-14339 (2013).
Abstract
Frédérique Pourpoint, Xiao Hua, Derek S. Middlemiss, Paul Adamson, Da Wang, Peter G. Bruce, and Clare P. Grey
New insights into the crystal and electronic structures of Li_1+xV_1-xO₂ from solid state NMR, pair distribution function analyses, and first principles calculations,
Chem. Mater. 24, 2880-2893 (2012).
Abstract
Y. Liang, B. Böhme, A. Ormeci, H. Borrmann, O. Pecher, F. Haarmann, W. Schnelle, M. Baitinger, and Yu. Grin
A Clathrate-I phase with Li-Ge framework,
Chem. Eur. J 18, 9818-9822 (2012).
Abstract
Sylvio Indris, Paul Heitjans, Reinhard Uecker, and Bernhard Roling
Li ion dynamics in a LiAlO₂ single crystal studied by ⁷Li NMR spectroscopy and conductivity measurements,
J. Phys. Chem. C 116, 14243-14247 (2012).
Abstract
M. Wilkening, E. Romanova, S. Nakhal, D. Weber, M. Lerch, P. Heitjans
Time-resolved and site-specific insights into migration pathways of Li⁺ in α-Li₃VF₆ by ⁶Li 2D exchange MAS NMR,
J. Phys. Chem. C 114, 19083-19088 (2010).
Abstract
O. Pecher, S.-T. Kong, T. Goebel, V. Nickel, K. Weichert, C. Reiner, H.-J. Deiseroth, J. Maier, F. Haarmann, and D. Zahn
Atomistic characterization of Li⁺ mobility and conductivity in Li_7-xP_6-xI_x Argyrodites from molecular dynamics simulations, solid-state NMR and impedance spectroscopy,
Chem. Eur. J. 16, 8347-8354 (2010).
Abstract
D. Bräunling, O. Pecher, D. M. Trots, A. Senyshyn, D. A. Zherebtsov, F. Haarmann, and R. Niewa
Synthesis, crystal structure and lithium motion of Li₈SeN₂ and Li₈TeN₂,
Z. Anorg. Allg. Chem. 636, 936-946 (2010).
Abstract
M. Vijayakumar, Sebastien Kerisit, Zhenguo Yang, Gordon L. Graff, Jun Liu, Jesse A. Sears, Sarah D. Burton, Kevin M. Rosso, and Jianzhi Hu
Combined ^6,7Li NMR and molecular dynamics study of Li diffusion in Li₂TiO₃,
J. Phys. Chem. C 113, 20108-20116 (2009).
Abstract
A. Kuhn, E. Tobschall, and P. Heitjans
Li ion diffusion in nanocrystalline and nanoglassy LiAlSi₂O₆ and LiBO₂ – Structure-dynamics relations in two glass forming compounds ,
Z. Phys. Chem. 223, 1359-1377 (2009).
Abstract
Baris Key, Rangeet Bhattacharyya, Mathieu Morcrette, Vincent Seznéc, Jean-Marie Tarascon, and Clare P. Grey
Real-time NMR investigations of structural changes in silicon electrodes for lithium-ion batteries,
J. Am. Chem. Soc. 131, 9239-9249 (2009).
Abstract
W. Iwaniak, J. Fritzsche, M. Zukalová, R. Winter, M. Wilkening, and P. Heitjans
Li conductivity of nanocrystalline Li₄Ti₅O₁₂ prepared by a sol-gel method and high-energy ball milling,
Def. Diff. Forum 289-292, 565-570 (2009).
Abstract
P. Heitjans and M. Wilkening
Diffusion in nanocrystalline ion conductors studied by solid state NMR and impedance spectroscopies,
Def. Diff. Forum 283-286, 705-715 (2009).
Abstract
A. Kuhn, M. Wilkening, and P. Heitjans
Mechanically induced decrease of the Li conductivity in an alumosilicate glass,
Solid State Ionics 180, 302-307 (2009).
Abstract
M. Wilkening, A. Kuhn, and P. Heitjans
Tuning the Li diffusivity of poor ionic conductors by mechanical treatment: High Li conductivity of strongly defective LiTaO₃ nanoparticles,
J. Phys. Chem. C 112, 9291-9300 (2008).
Abstract
M. Wilkening, M. Masoud, and P. Heitjans
Li dynamics in amorphous LiNbO₃ as probed by solid state NMR on different length scales,
Diffusion Fundamentals 8, 5.1-5.7 (2008).
P. Heitjans, E. Tobschall, and M. Wilkening
Ion transport and diffusion in nanocrystalline and glassy ceramics - impedance and NMR spectroscopy measurements on Li ion conductors,
Eur. Phys. J. Special Topics 161, 97-108 (2008).
Abstract
M. Wilkening, A. Kuhn, and P. Heitjans
Atomic-scale measurement of ultraslow Li motions in glassy LiAlSi₂O₆ by two-time ⁶Li spin-alignment echo NMR,
Phys. Rev. B 78, 054303/1-054303/9 (2008).
Abstract
A. S. Cattaneo, R. P. Lima, C. E. Tambelli, C. J. Magon, V. R. Mastelaro, A. Garcia, J. E. de-Souza, A. S. S. de-Camargo, C. C. de-Araujo, J. F. Schneider, J. P. Donoso, and H. Eckert
Structural role of fluoride in the ion-conducting glass system B2O3-PbO-LiF studied by single- and double-resonance NMR,
J. Phys. Chem. C 112, 10462-10471 (2008).
L. S. Cahill, C. W. Kirby, and G. R. Goward
⁶Li{³¹P} rotational-echo, double-resonance studies of lithium ion site dynamics in Li₃V₂(PO₄)₃,
J. Phys. Chem. C 112, 2215-2221 (2008).
M. Wilkening and P. Heitjans
Li jump process in h-Li_0.7TiS₂ studied by two-time ⁷Li spin-alignment echo NMR and comparison with results on two-dimensional diffusion from nuclear magnetic relaxation,
Phys. Rev. B 77, 24311/1-24311/13 (2008).
M. Wilkening, D. Gebauer, and P. Heitjans
Diffusion parameters in single-crystalline Li₃N as probed by ⁶Li and ⁷Li spin-alignment echo NMR spectroscopy in comparison with results from ⁸Li β-radiation detected NMR,
J. Phys.: Condens. Matter 20, 22201/1-22201/5 (2008).
J. Wontcheu, W. Bensch, M. Wilkening, P. Heitjans, S. Indris, P. Sideris, C. P. Grey, S. Mankovsky, and H. Ebert
Tuning the structural and physical properties of Cr₂Ti₃Se₈ by lithium intercalation: A study of the magnetic properties and investigation of ion mobility with NMR spectroscopy,
J. Am. Chem. Soc. 130, 288-299 (2008).
G. T. K. Fey, P. Muralidharan, Y. D. Cho, P. C. Chang, H. M. Kao
Electrochemical performance and ⁷Li NMR studies on an inverse spinel LiNi_1/3Co_1/3Mn_1/3VO₄ for Li-ion batteries,
J. Power Sources 174, 1142-1146 (2007).
Paul Heitjans, Muayad Masoud, Armin Feldhoff, and Martin Wilkening
NMR and impedance studies of nanocrystalline and amorphous ion conductors: lithium niobate as a model system,
Faraday Discuss. 134, 67-82 (2007).
M. Wilkening, W. Iwaniak, J. Heine, V. Epp, A. Kleinert, M. Behrens, G. Nuspl, W. Bensch, and P. Heitjans
Microscopic Li self-diffusion parameters in the lithiated anode material Li_4+xTi₅O₁₂ (0 ≤ x ≤ 3) measured by ⁷Li solid state NMR ,
Phys. Chem. Chem. Phys. 9, 6199-6202 (2007).
D. L. Zeng, J. Cabana, J. L. Breger, W. S. Yoon, and C. P. Grey
Cation ordering in Li[Ni_xMn_xCo_(1-2x)]O₂-layered cathode materials: A nuclear magnetic resonance (NMR), pair distribution function, X-ray absorption spectroscopy, and electrochemical study,
Chem. Mater. 19, 6277-6289 (2007).
Vladimir K. Michaelis, Pedro M. Aguiar, and Scott Kroeker
Probing alkali coordination environments in alkali borate glasses by multinuclear magnetic resonance,
J. Non-Cryst. Solids 353, 2582-2590 (2007).
J. F. Zhu, N. Mosey, T. Woo, and Y. N. Huang
Study of the adsorption of toluene in zeolite LiNa-Y by solid-state NMR Spectroscopy,
J. Phys. Chem. C 111, 13427-13436 (2007).
S. P. Puls and H. Eckert
Spatial distribution of lithium ions in glasses studied by ⁷Li{⁶Li} spin echo double resonance,
Phys. Chem. Chem. Phys. 9, 3992-3998 (2007).
C. Lu, J. Z. Hu, J. H. Kwak, Z. G. Yang, R. M. Ren, T. Markmaitree, and L. L. Shaw
Study the effects of mechanical activation on Li-N-H systems with ¹H and ⁶Li solid-state NMR,
J. Power Sources 170, 419-424 (2007).
M. Wilkening, C. Mühle, M. Jansen, and P. Heitjans
Microscopic access to long-range diffusion parameters of the fast ion conductor Li₇BiO₆ by solid state ⁷Li stimulated echo NMR,
J. Phys. Chem. B 111, 8691-8694 (2007).
L. van-Wullen, T. Echelmeyer, H. W. Meyer, and D. Wilmer
The mechanism of Li-ion transport in the garnet Li₅La₃Nb₂O₁₂,
Phys. Chem. Chem. Phys. 9, 3298-3303 (2007).
R. Böhmer and F. Qi
Spin relaxation and ultra-slow Li motion in an aluminosilicate glass ceramic,
Solid State Nucl. Magn. Reson. 31, 28-34 (2007).
Z. Stoeva, B. Jager, R. Gomez, S. Messaoudi, M. Ben-Yahia, X. Rocquefelte, G. B. Hix, W. Wolf, J. J. Titman, R. Gautier, P. Herzig, D. H. Gregory
Crystal chemistry and electronic structure of the metallic lithium ion conductor, LiNiN,
J. Am. Chem. Soc. 129, 1912-1920 (2007).
M. Wilkening, R. Amade, W. Iwaniak, and P. Heitjans
Ultraslow Li diffusion in spinel-type structured Li₄Ti₅O₁₂ - A comparison of results from solid state NMR and impedance spectroscopy,
Phys. Chem. Chem. Phys. 9, 1239-1246 (2007).
S. Indris, P. Heitjans, R. Uecker, and T. Bredow
Local electronic structure in a LiAlO₂ single crystal studied with ⁷Li NMR spectroscopy and comparison with quantum chemical calculations,
Phys. Rev. B 74, 245120/1-245120/5 (2006).
M. Wilkening and P. Heitjans
Extremely slow cation exchange processes in Li₄SiO₄ probed directly by two-time ⁷Li stimulated-echo nuclear magnetic resonance spectroscopy,
J. Phys.: Condens. Matter 18, 9849-9862 (2006).
L. van-Wüllen, N. Sofina, L. Hildebrandt, C. Muhle, and M. Jansen
NMR studies of cation transport in the crystalline ion conductors MCF₃SO₃ (M = Li, Na) and Li₇TaO₆,
Solid State Ionics 177, 1665-1672 (2006).
K. Gotoh, M. Maeda, A. Nagai, A. Goto, M. Tansho, K. Hashi, T. Shimizu, and H. Ishida
Properties of a novel hard-carbon optimized to large size Li ion secondary battery studied by ⁷Li NMR,
J. Power Sources 162, 1322-1328 (2006).
K. Yamada, K. Kumano, and T. Okuda
Lithium superionic conductors Li₃InBr₆ and LiInBr₄ studied by ⁷Li, ¹¹⁵In NMR,
Solid State Ionics 177, 1691-1695 (2006).
S. Jost, M. Kühnen, and H. Günther
⁷Li and ¹³C solid-state NMR spectra of lithium cuprates,
Magn. Reson. Chem. 44, 909-916 (2006).
S. P. Puls and H. Eckert
Site discrimination in mixed-alkali glasses studied by cross-polarization NMR,
J. Phys. Chem. B 110, 14253-14261 (2006).
M. Letellier, F. Chevallier, and F. Béguin
In situ ⁷Li NMR during lithium electrochemical insertion into graphite and a carbon/carbon composite,
J. Phys. Chem. Solids 67, 1228-1232 (2006).
Martin Wilkening, Wilfried Küchler, and Paul Heitjans
From ultraslow to fast lithium diffusion in the 2D ion conductor Li_0.7TiS₂ probed directly by stimulated-echo NMR and nuclear magnetic relaxation,
Phys. Rev. Lett. 97, 65901/1-65901/4 (2006).
K. Nakamura, H. Ohno, K. Okamura, Y. Michihiro, T. Moriga, I. Nakabayashi, and T. Kanashiro
⁷Li NMR study on Li⁺ ionic diffusion and phase transition in Li_xCoO₂,
Solid State Ionics 177, 821-826 (2006).
P. D. Battle, C. P. Grey, J. A. Rodgers, and J. Sloan
Structural chemistry of Ln₂BaLiRuO₇ (Ln = La, Pr),
Solid State Sci. 8, 280-288 (2006).
L. S. Cahill, R. P. Chapman, J. F. Britten, and G. R. Goward
⁷Li NMR and two-dimensional exchange study of lithium dynamics in monoclinic Li₃V₂(PO₄)₃,
J. Phys. Chem. B 110, 7171-7177 (2006).
K. Arbi, M. A. Paris, and J. Sanz
Lithium exchange processes in the conduction network of the nasicon LiTi_2-xZr_x(PO₄)₃ series (0 <= x <= 2),
J. Phys. Chem. B 110, 6454-6457 (2006).
D. Capsoni, M. Bini, V. Massarotti, P. Mustarelli, F. Belotti, and P. Galinetto
Cation distribution in LiMgVO₄ and LiZnVO₄: Structural and spectroscopic study,
J. Phys. Chem. B 110, 5409-5415 (2006).
A. Y. H. Lo, R. W. Schurko, M. Vettraino, B. O. Skadtchenko, M. Trudeau, and D. M. Antonelli
Solid-state ²³Na and ⁷Li NMR investigations of sodium- and lithium-reduced mesoporous titanium oxides,
Inorg. Chem. 45, 1828-1838 (2006).
C. Chazel, M. Ménétrier, L. Croguennec, and C. Delmas
Coupled ion/electron hopping in Li_xNiO₂: A ⁷Li NMR study,
Inorg. Chem. 45, 1184-1191 (2006).
K. Nakamura, D. Nishioka, Y. Michihiro, M. Vijayakumar, S. Selvasekarapandian, and T. Kanashiro
⁷Li and ⁵¹V NMR study on Li⁺ ionic diffusion in lithium intercalated Li_xV₂O₅,
Solid State Ionics 177, 129-135 (2006).
F. Qi, C. Rier, R. Bohmer, W. Franke and P. Heitjans
Ion hopping in crystalline and glassy spodumene LiAlSi₂O₆: ⁷Li spin-lattice relaxation and ⁷Li echo NMR spectroscopy,
Phys. Rev. B 72, 104301/1-104301/11 (2005).
C. Chazel, M. Ménétrier, L. Croguennec, and C. Delmas
^6/7Li NMR study of the Li_1-zNi_1+zO₂ phases,
Magn. Reson. Chem. 43, 849-857 (2005).
M. Ménétrier, Y. Shao-Horn, A. Wattiaux, L. Fournes, and C. Delmas
Iron substitution in lithium-overstoichiometric "Li_1.1CoO₂": Combined ⁵⁷Fe Mossbauer and ⁷Li NMR spectroscopies studies,
Chem. Mater. 17, 4653-4659 (2005).
Martin Wilkening and Paul Heitjans
Ultraslow diffusion in polycrystalline h-LiTiS₂ studied by ⁷Li spin-alignment echo NMR spectroscopy,
Defect Diffus. Forum 237-240, 1182-1187 (2005).
X. Guo, S. Greenbaum, F. Ronci, and B. Scrosati
X-ray diffraction and ⁷Li nuclear magnetic resonance studies of iron- and cobalt-substituted LiNiO₂ prepared from inorganic transition metal nitrates,
Solid State Ionics 168, 37-49 (2004).
Abstract
F. Qi, G. Diezemann, H. Böhm, J. Lambert, and R. Böhmer
Simple modeling of dipolar coupled ⁷Li spins and stimulated-echo spectroscopy of single-crystalline beta-eucryptite,
J. Magn. Reson. 169, 225-239 (2004).
T. Bredow, P. Heitjans, and M. Wilkening
Electric field gradient calculations for Li_xTiS₂ and comparison with ⁷Li NMR results,
Phys. Rev. B 70, 115111/1-115111/11 (2004).
C. P. Grey and N. Dupré
NMR studies of cathode materials for lithium-ion rechargeable batteries,
Chem. Rev. 104, 4493-4512 (2004).
Abstract
M. J. Reddy and P. P. Chu
⁷Li NMR spectroscopy and ion conduction mechanism in mesoporous silica (SBA-15) composite poly(ethylene oxide) electrolyte,
J. Power Sources 135, 1-8 (2004).
C. Mignon, Y. Millot, and P. P. Man
Piezoelectric signal suppression by a composite-pulse sequence in NMR (PDF article, 191 Kb),
C. R. Chimie 7, 425-430 (2004).
P. Heitjans and S. Indris
Diffusion and ionic conduction in nanocrystalline ceramics,
J. Phys.: Condens. Matter 15, R1257-R1289 (2003).
M. Wilkening, S. Indris, and P. Heitjans
Heterogeneous lithium diffusion in nanocrystalline Li₂O:Al₂O₃ composites,
Phys. Chem. Chem. Phys. 5, 2225-2231 (2003).
C. P. Grey and Y. J. Lee
Lithium MAS NMR studies of cathode materials for lithium-ion batteries,
Solid State Sci. 5, 883-894 (2003).
R. Q. Fu, Z. R. Ma, J. P. Zheng, G. Au, E. J. Plichta, and C. H. Ye
High-resolution ⁷Li solid-state NMR study of Li_xV₂O₅ cathode electrodes for Li-rechargeable batteries,
J. Phys. Chem. B 107, 9730-9735 (2003).
N. A. Sergeev and A. M. Panich
Simple two-pulse time-reversal sequence for quadrupole-coupled spin system,
Z. Naturforsch. 58a, 33-35 (2003).
Anil Kumar, K. V. Ramanathan, T. S. Mahesh, Neeraj Sinha, and K. V. R. Murali
Developments in quantum information processing by nuclear magnetic resonance: Use of quadrupolar and dipolar couplings,
Pramana – J. Phys. 59, 243-254 (2002).
Abstract
M. Wilkening, D. Bork, S. Indris, and P. Heitjans
Diffusion in amorphous LiNbO₃ studied by ⁷Li NMR -- comparison with the nano- and microcrystalline material,
Phys. Chem. Chem. Phys. 4, 3246-3251 (2002).
H. Du, V. V. Terskikh, C. I. Ratcliffe, and J. A. Ripmeester
Distinguishing surface versus buried cation sites in aluminosilicate mesoporous materials,
J. Am. Chem. Soc. 124, 4216-4217 (2002).
F. Qi, T. Jörg, and R. Böhmer
Stimulated-echo NMR spectroscopy of ⁹Be and ⁷li in solids: method and application to ion conductors,
Solid State Nucl. Magn. Reson. 22, 484-500 (2002).
R. Siegel, J. Hirschinger, D. Carlier, S. Matar, M. Ménétrier, and C. Delmas
⁵⁹Co and ^6,7Li MAS NMR in polytypes O2 and O3 of LiCoO₂,
J. Phys. Chem. B 105, 4166-4174 (2001).
Manuel Sanchez-Sanchez and Teresa Blasco
Pyrrole as an NMR probe molecule to characterise zeolite basicity,
Chem. Commun.491-492 (2000).
Abstract
R. Böhmer
Multiple-time correlation functions in spin-3/2 solid-state NMR spectroscopy,
J. Magn. Reson. 147, 78-88 (2000).
R. Böhmer, T. Jörg, F. Qi, and A. Titze
Stimulated ⁷Li echo NMR spectroscopy of slow ionic motions in a solid electrolyte,
Chem. Phys. Lett. 316, 419-424 (2000).
H. W. Shin, S. H. Choh, T. H. Yeom, K. S. Hong, and D. Y. Han
1D nutation NMR of ⁷Li in LiTaO₃ and LiNbO₃ single crystals and powders,
J. Korean Phys. Soc. 32, S662-S664 (1998).

Recent NMR reviews

Lithium-6 and lithium-7 NMR
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Solid-state lithium NMR references

Solid-state NMR bibliography for

Lithium-6 and lithium-7 NMR 鋰

Solid-state lithium NMR references

Solid-state NMR bibliography for

Lithium-6 and lithium-7 NMR
鋰