Copper-63 and copper-65 NMR references

Isotope	Spin	Natural abundance (%)	Quadrupole moment (10^-30m²)	Relative sensitivity	Absolute sensitivity	NMR frequency (MHz) at a field of 2.3488T	Reference sample
Cu-63	3/2	69.09	-22.0	9.31E-2	6.43E-2	-26.505	[Cu(CH₃CN)₄][ClO₄]
Cu-65	3/2	30.91	-20.4	0.11	3.52E-2	-28.394

Solid-state copper NMR references

Huaguang Yu, Xiuzhen Tan, Guy M. Bernard, Victor V. Terskikh, Jinglin Chen, and Roderick E. Wasylishen
Solid-state ⁶³Cu, ⁶⁵Cu and ³¹P NMR spectroscopy of photoluminescent copper(I) triazole phosphine complexes,
J. Phys. Chem. A 119, 8279-8293 (2015).
Abstract
Léo Choubrac, Michaël Paris, Alain Lafond, Catherine Guillot-Deudon, Xavier Rocquefelte, and Stéphane Jobic
Multinuclear (⁶⁷Zn, ¹¹⁹Sn and ⁶⁵Cu) NMR spectroscopy – an ideal technique to probe the cationic ordering in Cu₂ZnSnS₄ photovoltaic materials,
Phys. Chem. Chem. Phys. 15, 10722-10725 (2013).
Abstract
J. A. Lehmann-Horn, D. G. Miljak, and T. J. Bastow
⁷⁵As, ⁶³Cu NMR and NQR characterization of selected arsenic minerals,
Solid State Nucl. Magn. Reson. 54, 8-12 (2013).
Abstract
Bryan E. G. Lucier, Joel A. Tang, Robert W. Schurko, Graham A. Bowmaker, Peter C. Healy, and John V. Hanna
Solid-state ⁶⁵Cu and ³¹P NMR spectroscopy of bis(triphenylphosphine) copper species,
J. Phys. Chem. C 114, 7949-7962 (2010).
Abstract
J. P. Yesinowski, H. D. Ladouceur, A. P. Purdy, and J. B. Miller
Electrical and ionic conductivity effects on magic-angle spinning nuclear magnetic resonance parameters of CuI,
J. Chem. Phys. 133, 234509/1-234509/18 (2010).
Abstract
Luke A. O’Dell, Aaron J. Rossini, and Robert W. Schurko
Acquisition of ultra-wideline NMR spectra from quadrupolar nuclei by frequency stepped WURST–QCPMG,
Chem. Phys. Lett. 468, 330-335 (2009).
Abstract
T. J. Bastow and S. Celotto
²⁵Mg NMR site analysis in metals and intermetallics,
Solid State Nucl. Magn. Reson. 35, 217-222 (2009).
Abstract
T. F. Kemp and M. E. Smith
QuadFit—A new cross-platform computer program for simulation of NMR line shapes from solids with distributions of interaction parameters,
Solid State Nucl. Magn. Reson. 35, 243-252 (2009).
Abstract
R. R. Gainov, A. V. Dooglav, I. N. Pen’kov, I. R. Mukhamedshin, A. V. Savinkov, and N. N. Mozgova
Copper valence, structural separation and lattice dynamics in tennantite (fahlore): NMR, NQR and SQUID studies,
Phys. Chem. Miner. 35, 37-48 (2008).
Abstract
E. N. Muhamad, R. Irmawati, Y. H. Tautiq-Yap, A. H. Abdullah, B. L. Kniep, F. Girgsdies, and T. Ressler
Comparative study of Cu/ZnO catalysts derived from different precursors as a function of aging,
Catal. Today 131, 118-124 (2008).
J. A. Tang, B. D. Ellis, T. H. Warren, J. V. Hanna, C. L. B. Macdonald, and R. W. Schurko
Solid-state ⁶³Cu and ⁶⁵Cu NMR spectroscopy of inorganic and organometallic copper(I) complexes,
J. Am. Chem. Soc. 129, 13049-13065 (2007).
F. Haarmann, M. Armbruster, and Y. Grin
Local ordering in the intermetallic compound Cu_1-xAl₂ studied by NMR spectroscopy,
Chem. Mater. 19, 1147-1153 (2007).
D. Rusanova, K. J. Pike, I. Persson, R. Dupree, M. Lindberg, J. V. Hanna, O. N. Antzutkin, and W. Forsling
Solid-state static ⁶⁵Cu and ³¹P CP/MAS NMR, and liquid-state EXAFS studies on copper(I) O,O'-dialkyldithiophosphate cluster compounds: Formation of the copper(I) O,O'-di-iso-amyldlthiophosphate cluster compound on the surface of,
Polyhedron 25, 3569-3580 (2007).
D. Rusanova, K. J. Pike, R. Dupree, J. V. Hanna, O. N. Antzutkin, I. Persson, and W. Forsling
Spectroscopic characterization of the polycrystalline copper(I) di-n-butyldithlophosphate cluster - Cu₈[S₂P(O-n-Bu)₂]₆(mu₈-S): Solid-state ³¹P CP/MAS and static ⁶⁵Cu NMR studies,
Inorg. Chim. Acta 359, 3903-3910 (2006).
Abstract
D. Rusanova, W. Forsling, O. N. Antzutkin, K. J. Pike, and R. Dupree
Solid-state ³¹P CP/MAS and static ⁶⁵Cu NMR characterization of polycrystalline copper(I) dialkyldithiophosphate clusters,
J. Magn. Reson. 179, 140-145 (2006).
Gunther Brunklaus, Jerry C. C. Chan, Hellmut Eckert, Sara Reiser, Tom Nilges, and Arno Pfitzner
NMR studies of phosphorus chalcogenide–copper iodide coordination compounds,
Phys. Chem. Chem. Phys. 5, 3768-3776 (2003).
Abstract
T. Shimizu, T. Matsumoto, A. Goto, T. V. C. Rao, K. Yoshimura, and K. Kosuge
Spin susceptibility and superexchange interaction in the antiferromagnet CuO,
Phys. Rev. B 68, 224433/1-224433/8 (2003).
T. J. Bastow and S. Celotto
Clustering and formation of nano-precipitates in dilute aluminium and magnesium alloys,
Mater. Sci. Eng. C 23, 757-762 (2003).
A. Egorov, I. R. Mukhamedshin, and H. Suzuki
NMR powder spectra in case of strong quadrupole interaction,
Physica B 329-333, 1397-1398 (2003).
T. J. Bastow and S. Celotto
Structure evolution in dilute Al(Cu) alloys observed by ⁶³Cu NMR,
Acta Mater. 51, 4621-4630 (2003).
Sara Reiser, Gunther Brunklaus, Jung Hoon Hong, Jerry C. C. Chan, Hellmut Eckert, and Arno Pfitzner
(CuI)₃P₄S₄ : Preparation, structural, and NMR spectroscopic characterization of a copper(I) halide adduct with β-P₄S₄,
Chem. Eur. J. 8, 4228-4233 (2002).
Abstract
Y. Furukawa, S. Takada, K. Kumagai, T. Kawashima, E. Takayama-Muromachi, N. Kobayashi, T. Fukase, K. Chiba, and T. Goto
NMR studies of magnetic superconductor RuSr₂RECu₂O₈ (RE = Gd, Eu and Y),
J. Phys. Chem. Solids 63, 2315-2318 (2002).
S. Sakida, N. Kato, and Y. Kawamoto
⁶³Cu magic angle spinning (MAS) nuclear magnetic resonance (NMR) study of CuX crystals (X = Cl, Br, and I) and CuX-based glasses (X = Cl, Br, and I),
Mater. Res. Bull. 37, 2263-2274 (2002).
P. E. Stallwortha, J.-F. Guillemoles, J. Flowers, J. Vedel, and S. G. Greenbaum
NMR studies of CuInS₂ and CuInSe₂ crystals grown by the Bridgman method,
Solid State Commun. 113, 527-532 (2000).
Abstract
P. R. Bodart, J.-P. Amoureux, Y. Dumazy, and R. Lefort
Theoretical and experimental study of quadrupolar echoes for half-integer spins in static solid-state NMR,
Mol. Phys. 98, 1545-1551 (2000).
A. A. Gippius, E. V. Antipov, W. Hoffmann, K. Lüders, and G. Buntkowsky
Low-frequency spin dynamics as probed by ⁶³Cu and ¹⁹⁹Hg NMR in HgBa₂CuO_4+delta superconductors with different oxygen content,
Phys. Rev. B 59, 654-660 (1999).
V. N. Berzhanskii, A. I. Gorbovanov, and S. N. Polulyakh
Multiquantum triple-pulse spin-echo signals from quadrupole nuclei in magnetically ordered substances,
JETP 88, 1151-1154 (1999).
J. Haase, N. J. Curro, R. Stern, and C. P. Slichter
New double resonance technique for quadrupolar nuclei,
Mol. Phys. 95, 891-896 (1998).
Abstract
S. Hayashi and K. Hayamizu
Effect of spinning on chemical shifts in magic-angle-spinning nuclear magnetic resonance,
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D. Köngeter, F. Hentsch, H. Seidel, M. Mehring, P. Erk, and S. Hünig
Metal like ¹³C and ⁶³Cu Knight shifts in the organic conductor (2,5-dimethyl-dicyanoquinonediimine)₂Cu,
Solid. State Commun. 65, 453-456 (1988).

Related bibliography

M. J. Willans, D. N. Sears, and R. E. Wasylishen
The effectiveness of ¹H decoupling in the ¹³C MAS NMR of paramagnetic solids: An experimental case study incorporating copper(II) amino acid complexes,
J. Magn. Reson. 191, 31-46 (2008).
H. Fukazawa, N. Yamatoji, Y. Kohori, C. Terakura, N. Takeshita, Y. Tokura, and H. Takagi
Manometer extension for high pressure measurement: Nuclear quadrupole resonance study of Cu₂O with a modified Bridgman anvil cell up to 10 GPa,
Rev. Sci. Instr. 78, 15160-1/15160-4 (2007).
Scott Kroeker, John V. Hanna, Roderick E. Wasylishen, Eric W. Ainscough, and Andrew M. Brodie
Anisotropy in the ³¹P, ^63/65Cu indirect spin–spin coupling and ³¹P nuclear shielding tensors of linear copper(I) phosphines,
J. Magn. Reson. 135, 208-215 (1998).
Abstract
F. Asaro, A. Camus, R. Gobetto, A. C.Olivieri, and G. Pellizer
⁶³Cu-³¹P coupling constants and ⁶³Cu quadrupole couplings from ³¹P CP/MAS spectra of copper (I)—phosphine complexes with aryldithiocarboxylates or benzoate,
Solid State Nucl. Magn. Reson. 8, 81-88 (1997).
Abstract
Kazunaka Endo, Kyonosuke Yamamoto, Kenzo Deguchi, and Kazuhiro Matsushita
⁶³Cu high resolution NMR of Cu(I) halides in aqueous solution and suspension,
Bull. Chem. Soc. Jpn 60, 2803-2807 (1987).
Abstract

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Copper-63 and copper-65 NMR
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