NMR pulse sequence:
MQ-MAS signal enhancement with Quadrupolar CPMG




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MQ Quadrupolar Carr Purcell Meiboom Gill MAS

Larsen and coworkers introduced CPMG sequence into MQMAS experiment, that is, a train of selective rotor-synchronized Pi pulses during the MQMAS acquisition period.

The central-transition MAS echoes are successively accumulated to enhance the overall intensity. This approach generates sidebands along the F2 dimension.

Amplitude modulated split-t1 preparation for PFG 3QMAS

This figure represents the amplitude-modulated split-t1 preparation for 3Q-QCPMG-MAS sequence applied to spin I = 3/2.

Selecting both pathways should generate pure absorption 2D lineshape.

ACQUISITION: Hyper-complex or TPPI

Split-t1 approach avoids shearing transformation.

Amplitude modulated split-t1 preparation for PFG 3QMAS

This figure represents the amplitude-modulated split-t1 preparation for 3Q-QCPMG-MAS sequence applied to spin I = 5/2.

Selecting both pathways should generate pure absorption 2D lineshape.

ACQUISITION: Hyper-complex or TPPI

Split-t1 approach avoids shearing transformation.


Lefort and coworkers introduced a z-filter preparation for 3Q-QCPMQ-MAS experiment.

Amplitude modulated z-filter preparation for PFG 3QMAS

This figure represents the z-filter preparation for 3Q-QCPMG-MAS sequence applied to spin I = 5/2. The echo and anti-echo signals are observed.

ACQUISITION: Hyper-complex or TPPI

Shearing transformation is required to obtain 2D isotropic (in F1 dimension) anisotropic (in the F2 dimension) correlation spectrum.

 

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