Ruthenium-99 and ruthenium-101 NMR




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Isotope Spin Natural
abundance(%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
Ru-99 5/2 12.72 7.9 1.95E-4 2.48E-5 4.605 K4[Ru(CN)6]
Ru-101 5/2 17.07 45.7 1.41E-3 2.40E-4 5.161

Solid-state ruthenium NMR references

  1. Z. H. Han, J. I. Budnick, W. A. Hines, B. Dabrowski, and T. Maxwell
    Nuclear magnetic resonance study of the Ru/Mn valence states and magnetic interactions in SrRu0.9Mn0.1O3,
    Appl. Phys. Lett. 89, 102501/1-102501/3 (2006).
    zhaohui_han@urmc.rochester.edu
     
  2. K. J. Ooms and R. E. Wasylishen
    Solid-state Ru-99 NMR spectroscopy: A useful tool for characterizing prototypal diamagnetic ruthenium compounds,
    J. Am. Chem. Soc. 126, 10972-10980 (2004).
    roderick.wasylishen@ualberta.ca
     
  3. H. Sakai, N. Osawa, K. Yoshimura, M. H. Fang, and K. Kosuge
    99,101Ru NMR study of EuSr2RuCu2O8: coexistence of ferromagnetism and superconductivity,
    Phys. Rev. B 67, 184409/1-184409/6 (2003).
    sakai@kuchem.kyoto-u.ac.jp
     
  4. Y. Furukawa, S. Takada, K. Kumagai, T. Kawashima, E. Takayama-Muromachi, N. Kobayashi, T. Fukase, K. Chiba, and T. Goto
    NMR studies of magnetic superconductor RuSr2RECu2O8 (RE = Gd, Eu and Y),
    J. Phys. Chem. Solids 63, 2315-2318 (2002).
    furu@phys.sci.hokudai.ac.jp
     
  5. H. Sakai, N. Osawa, K. Yoshimura, M. H. Fang, and K. Kosuge
    99,101Ru NMR study of EuSr2RuCu2O8,
    Physica C 378-381, 399-403 (2002).
    sakai@kuchem.kyoto-u.ac.jp
     
  6. H. Sakai, K. Yoshimura, H. Kato, S. Kambe, and R. E. Walstedt
    NMR study of metallic pyrochlore ruthenium oxides, Bi2Ru2O7 and Pb2Ru2O7-d,
    J. Phys. Chem. Solids 63, 1039-1041 (2002).
    sakai@kuchem.kyoto-u.ac.jp
     
  7. H. Mukuda, K. Ishida, Y. Kitaoka, K. Asayama, R. Kanno, and M. Takano
    Spin fluctuations in the ruthenium oxides RuO2, SrRuO3, CaRuO3, and Sr2RuO4 probed by Ru NMR,
    Phys. Rev. B 60, 12279-12285 (1999).
     
  8. K. Ishida, Y. Kawasaki, Y. Kitaoka, K. Asayama, H. Nakamura, and J. Flouquet
    Ru NMR and NQR probes of the metamagnetic transition in CeRu2Si2,
    Phys. Rev. B 57, R11054-R11057 (1998).
     

Related bibliography

  1. P. Granger, T. Richert, K. Elbayed, P. Kempgens, J. Hirschinger, J. Raya, J. Rosť, and P. Braunstein
    Microdynamic motion of tetrahedral clusters studied by 59Co and 99Ru NMR relaxations,
    Molec. Phys. 92, 895-902 (1997).
     
  2. Wai-Yeung Wong and Wing-Tak Wong
    Ruthenium 1993,
    Coord. Chem. Rev. 146, A307-A384 (1995).
     
 

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