Rubidium-85 and rubidium-87 NMR




Home and Applets > Periodic Table > Rubidium
Isotope Spin Natural
abundance(%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
Rb-85 5/2 72.15 27.6 1.05E-2 7.57E-3 -9.655 RbCl
Rb-87 3/2 27.85 13.35 0.17 4.87E-2 -32.721

Directory of solid-state Rb-85 and Rb-87 NMR references
Single Crystal Crystalline Powder
Rb2CrO4, RbVO3, Salt
Amorphous Powder

Solid-state rubidium NMR references

  1. Thorsten Goebel, Alim Ormeci, Oliver Pecher, and Frank Haarmann
    The silicides M4Si4 with M = Na, K, Rb, Cs, and Ba2Si4 – NMR spectroscopy and quantum mechanical calculations,
    Z. Anorg. Allg. Chem. 638, 1437-1445 (2012).
    Abstract
     
  2. Thorsten Goebel, Yurii Prots, Alim Ormeci, Oliver Pecher, and Frank Haarmann
    Synthesis, crystal structure and chemical bonding of the Zintl phase Rb7NaSi8,
    Z. Anorg. Allg. Chem. 637, 1982-1991 (2011).
    Abstract
     
  3. L. A. O'Dell, K. J. Harris, and R. W. Schurko
    Optimized excitation pulses for the acquisition of static NMR powder patterns from half-integer quadrupolar nuclei,
    J. Magn. Reson. 203, 156-166 (2010).
    Abstract
     
  4. Krishna K. Dey, Jason T. Ash, Nicole M. Trease, and Philip J. Grandinetti
    Trading sensitivity for information: Carr–Purcell–Meiboom–Gill acquisition in solid-state NMR,
    J. Chem. Phys. 133, 054501/1-054501/10 (2008).
    Abstract
     
  5. Joel A. Tang, Luke A. O’Dell, Pedro M. Aguiar, Bryan E. G. Lucier, Dimitris Sakellariou, and Robert W. Schurko
    Application of static microcoils and WURST pulses for solid-state ultra-wideline NMR spectroscopy of quadrupolar nuclei ,
    Chem. Phys. Lett. 466, 227-234 (2008).
    Abstract
     
  6. Luke A. O’Dell and Robert W. Schurko
    QCPMG using adiabatic pulses for faster acquisition of ultra-wideline NMR spectra,
    Chem. Phys. Lett. 464, 97-102 (2008).
    Abstract
     
  7. M. J. Thrippleton, T. J. Ball, and S. Wimperis
    Satellite transitions acquired in real time by magic angle spinning (STARTMAS): "Ultrafast" high-resolution MAS NMR spectroscopy of spin I = 3/2 nuclei ,
    J. Chem. Phys. 128, 34507/1-34507/9 (2008).
     
  8. Krishna K. Dey, S. Prasad, Jason T. Ash, Michael Deschamps, and Philip J. Grandinetti
    Spectral editing in solid-state MAS NMR of quadrupolar nuclei using selective satellite inversion,
    J. Magn. Reson. 185, 326-330 (2007).
    Abstract
     
  9. R. Bhattacharyya and L. Frydman
    Quadrupolar nuclear magnetic resonance spectroscopy in solids using frequency-swept echoing pulses,
    J. Chem. Phys. 127, 194503/1-194503/8 (2007).
     
  10. Vladimir K. Michaelis, Pedro M. Aguiar, and Scott Kroeker
    Probing alkali coordination environments in alkali borate glasses by multinuclear magnetic resonance,
    J. Non-Cryst. Solids 353, 2582-2590 (2007).
     
  11. T. J. Ball and S. Wimperis
    Use of SPAM and FAM pulses in high-resolution MAS NMR spectroscopy of quadrupolar nuclei,
    J. Magn. Reson. 187, 343-351 (2007).
     
  12. J. Trebosc, J.-P. Amoureux, and Z. H. Gan
    Comparison of high-resolution solid-state NMR MQMAS and STMAS methods for half-integer quadrupolar nuclei,
    Solid State NMR 31, 1-9 (2007).
    jean-paul.amoureux@univ-lille1.fr
     
  13. R. Siegel, T. T. Nakashima, and R. E. Wasylishen
    Sensitivity enhancement of NMR spectra of half-integer spin quadrupolar nuclei in solids using hyperbolic secant pulses,
    J. Magn. Reson. 184, 85-100 (2007).
    Roderick.wasylishen@ualberta.ca
     
  14. T. Vosegaard, C. Kehlet, N. Khaneja, S. J. Glaser, and N. C. Nielsen
    Improved excitation schemes for multiple-quantum magic-angle spinning for quadrupolar nuclei designed using optimal control theory,
    J. Am. Chem. Soc. 127, 13768-13769 (2005).
    tv@ehem.au.dk; nen@chem.au.dk
     
  15. S. E. Ashbrook and S. Wimperis
    Rotor-synchronized acquisition of quadrupolar satellite-transition NMR spectra: practical aspects and double-quantum filtration,
    J. Magn. Reson. 177, 44-55 (2005).
    s.wimperis@exeter.ac.uk
     
  16. N. Malicki, L. Mafra, A.-A. Quoineaud, J. Rocha, F. Thibault-Starzyk, and C. Fernandez
    Multiplex MQMAS NMR of quadrupolar nuclei,
    Solid State NMR 28, 13-21 (2005).
    christian.fernandez@ensicaen.fr
     
  17. J.-P. Amoureux, L. Delevoye, G. Fink, F. Taulelle, A. Flambard, and L. Montagne
    Implementing SPAM into STMAS: a net sensitivity improvement in high-resolution NMR of quadrupolar nuclei,
    J. Magn. Reson. 175, 285-299 (2005).
    jean-paul.amoureux@univ-lille1.fr
     
  18. B. O. Skadtchenko, M. Trudeau, R. W. Schurko, A. Y. H. Lo, and D. M. Antonelli
    Electronic properties and solid-state 87Rb and 13C NMR studies of mesoporous tantalum oxide rubidium fulleride composites,
    Chem. Mater. 17, 1467-1478 (2005).
     
  19. Renée Siegel, T. T. Nakashima, and R. E. Wasylishen
    Sensitivity enhancement of MQMAS NMR spectra of spin 3/2 nuclei using hyperbolic secant pulses,
    Chem. Phys. Lett. 403, 353-358 (2005).
    roderick.wasylishen@ualberta.ca
     
  20. R. Siegel, T. T. Nakashima, and R. E. Wasylishen
    Signal enhancement of NMR spectra of half-integer quadrupolar nuclei in solids using hyperbolic secant pulses,
    Chem. Phys. Lett. 388, 441-445 (2004).
    roderick.wasylishen@ualberta.ca
     
  21. R. W. Schurko, I. Hung, and C. M. Widdifield
    Signal enhancement in NMR spectra of half-integer quadrupolar nuclei via DFS-QCPMG and RAPT-QCPMG pulse sequences,
    Chem. Phys. Lett. 379, 1-10 (2003).
    rschurko@uwindsor.ca
     
  22. H. T. Kwak and Z. H. Gan
    Double-quantum filtered STMAS,
    J. Magn. Reson. 164, 369-372 (2003).
    gan@magnet.fsu.edu
     
  23. S. E. Ashbrook and S. Wimperis
    SCAM-STMAS: satellite-transition MAS NMR of quadrupolar nuclei with self-compensation for magic-angle misset,
    J. Magn. Reson. 162, 402-416 (2003).
    s.wimperis@exeter.ac.uk
     
  24. J.-P. Amoureux, C. Morais, J. Trebosc, J. Rocha, and C. Fernandez
    I-STMAS, a new high-resolution solid-state NMR method for half-integer quadrupolar nuclei,
    Solid State NMR 23, 213-223 (2003).
    jean-paul.amoureux@univ-lille1.fr; christian.fernandez@ismra.fr
     
  25. P. K. Madhu, K. J. Pike, R. Dupree, M. H. Levitt, and M. E. Smith
    Modulation-aided signal enhancement in the magic angle spinning NMR of spin-5/2 nuclei,
    Chem. Phys. Lett. 367, 150-156 (2003).
    mhl@soton.ac.uk; m.e.smith.1@warwick.ac.uk
     
  26. A. Jerschow and R. Kumar
    Calculation of coherence pathway selection and cogwheel cycles,
    J. Magn. Reson. 160, 59-64 (2003).
    alexej.jerschow@nyu.edu
     
  27. R. Lefort, J. W. Wiench, M. Pruski, and J.-P. Amoureux
    Optimization of data acquisition and processing in Carr-Purcel-Meiboom-Gill MQMAS NMR,
    J. Chem. Phys. 116, 2493-2501 (2002).
    mpruski@iastate.edu
     
  28. S. Wi, J. W. Logan, D. Sakellariou, J. D. Walls, and A. Pines
    Rotary resonance recoupling for half-integer quadrupolar nuclei in solid-state nuclear magnetic resonance spectroscopy,
    J. Chem. Phys. 117, 7024-7033 (2002).
    pines@cchem.berkeley.edu
     
  29. S. E. Ashbrook and S. Wimperis
    Satellite-transition MAS NMR of spin I = 3/2, 5/2, 7/2, and 9/2 nuclei: sensitivity, resolution, and practical implementation,
    J. Magn. Reson. 156, 269-281 (2002).
    s.wimperis@exeter.ac.uk
     
  30. D. D. Laws, H.-M. L. Bitter, and A. Jerschow
    Solid-state NMR spectroscopic methods in chemistry,
    Angew. Chem. Int. Ed. 41, 3096-3129 (2002).
    alexej.jerschow@nyu.edu
     
  31. D. Massiot, F. Fayon, M. Capron, I. King, S. Le Calvé, B. Alonso, J.-O. Durand, B. Bujoli, Z. Gan, and G. Hoatson
    Modelling one- and two-dimensional solid-state NMR spectra,
    Magn. Reson. Chem. 40, 70-76 (2002).
    massiot@cnrs-orleans.fr
     
 

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