Vanadium-51 NMR

Home and Applets > Periodic Table > Vanadium
Isotope Spin Natural
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
V-50 6 0.24 21.0 5.55E-2 1.33E-4 -9.970 VOCl3
V-51 7/2 99.76 -5.2 0.38 0.38 -26.289

Directory of solid-state V-51 NMR references
Single Crystal Crystalline Powder
Complex, Oxide, V2O5
Amorphous Powder

Solid-state vanadium NMR references

  1. E. Nimerovsky, R. Gupta, J. Yehl, M. Li, T. Polenova, A. Goldbourt
    Phase-modulated LA-REDOR: A robust, accurate and efficient solid-state NMR technique for distance measurements between a spin-1/2 and a quadrupole spin,
    J. Magn. Reson. 244, 107-113 (2014).
  2. Klaus Eichele and Arnd-Rüdiger Grimmer
    Phosphorus-31 and vanadium-51 solid-state nuclear magnetic resonance spectroscopy of β-vanadyl phosphate — Effects of homo- and heteronuclear spin-spin, electrostatic, and paramagnetic interactions,
    Can. J. Chem. 89, 870-884 (2011).
  3. Jörg Frey, Yean Sang Ooi, Bejoy Thomas, V. R. Reddy Marthala, Arne Bressel, Thomas Schölkopf, Thomas Schleid, and Michael Hunger
    Vanadium phosphates on mesoporous supports: model catalysts for solid-state NMR studies of the selective oxidation of n-butane,
    Solid State Nucl. Magn. Reson. 35, 130-137 (2009).
  4. Maria Wächtler, Annika Schweitzer, Torsten Gutmann, Hergen Breitzke, and Gerd Buntkowsky
    Efficient analysis of 51V solid-state MAS NMR spectra using genetic algorithms,
    Solid State Nucl. Magn. Reson. 35, 37-48 (2009).
  5. O. B. Lapina, D. F. Khabibulin, A. A. Shubin, and V. V. Terskikh
    Practical aspects of 51V and 93Nb solid-state NMR spectroscopy and applications to oxide materials,
    Prog. Nucl. Magn. Reson. Spectrosc. 53, 128-191 (2008).
  6. I. A. Garifullin, N. N. Garif'yanov, R. I. Salikhov, and L. R. Tagirov
    Knight shift in superconducting vanadium,
    JETP Lett. 87, 316-320 (2008).
  7. A. E. Lewandowska, M. A. Banares, M. Ziolek, D. F. Khabibulin, and O. B. Lapina
    Structural and reactive relevance of V + Nb coverage on alumina of V-Nb-O/Al2O3 catalytic systems,
    J. Catal. 255, 94-103 (2008).
  8. S. E. Bolte, K. J. Ooms, T. Polenova, B. Baruah, D. C. Crans, J. J. Smee
    51V solid-state NMR and density functional theory studies of vanadium environments in V(V)O2 dipicolinic acid complexes ,
    J. Chem. Phys. 128, 52317/1-52317/11 (2008).
  9. D. Khabibulin, K. Romanenko, M. Zuev, and O. Lapina
    Solid state NMR characterization of individual compounds and solid solutions formed in Sc2O3-V2O5-Nb2O5-Ta2O5 system,
    Magn. Reson. Chem. 45, 962-970 (2008).
  10. Dieter Rehder, Tatyana Polenova, and Michael Buhl
    Vanadium-51 NMR,
    Annu. Rep. NMR Spectros. 62, 49-114 (2007).
  11. Kristopher J. Ooms, Stephanie E. Bolte, Jason J. Smee, Bharat Baruah, Debbie C. Crans, and Tatyana Polenova
    Investigating the vanadium environments in hydroxylamido V(V) dipicolinate complexes using 51V NMR spectroscopy and density functional theory,
    Inorg. Chem. 46, 9285-9293 (2007).
  12. Z. Szalay and J. Rohonczy
    A multinuclear NMR study of sodium-borovanadophosphate glasses,
    J. Non-Cryst. Solids 353, 295-301 (2007).
  13. K. Scheurell, G. Scholz, and E. Kemnitz
    Structural study of VOx doped aluminium fluoride and aluminium oxide catalysts,
    Solid State Chem. 180, 749-758 (2007).
  14. S. Ferdov, Z. Lin, and R. A. S. Ferreira
    Incorporation of mixed valence vanadium in the microporous titanosilicate AM-2,
    Microporous Mesoporous Mater. 96, 363-368 (2006).
  15. Becky Gee
    Vanadium-51 solid state NMR electric field gradient tensors: A DFT embedded ion and isolated cluster study of crystalline vanadium oxides,
    Solid State Nucl. Magn. Reson. 30, 171-181 (2006).
  16. S. Shylesh and A. P. Singh
    Vanadium-containing ethane-silica hybrid periodic mesoporous organosilicas: Synthesis, structural characterization and catalytic applications,
    Microporous Mesoporous Mater. 94, 127-138 (2006).
  17. T. Radhika and S. Sugunan
    Structural and catalytic investigation of vanadia supported on ceria promoted with high surface area rice husk silica,
    J. Phys. Chem. A 250, 169-176 (2006).
  18. N. Pooransingh-Margolis, R. Renirie, Z. Hasan, R. Wever, A. J. Vega, and T. Polenova
    51V solid-state magic angle spinning NMR spectroscopy of vanadium chloroperoxidase,
    J. Am. Chem. Soc. 128, 5190-5208 (2006).
  19. D. Capsoni, M. Bini, V. Massarotti, P. Mustarelli, F. Belotti, and P. Galinetto
    Cation distribution in LiMgVO4 and LiZnVO4: Structural and spectroscopic study,
    J. Phys. Chem. B 110, 5409-5415 (2006).
  20. K. Nakamura, D. Nishioka, Y. Michihiro, M. Vijayakumar, S. Selvasekarapandian, and T. Kanashiro
    7Li and 51V NMR study on Li+ ionic diffusion in lithium intercalated LixV2O5,
    Solid State Ionics 177, 129-135 (2006).
  21. Stanislaw Dzwigaj and Michel Che
    Oxidation state of vanadium introduced in dealuminated zeolite by impregnation with VIVOSO4 solution: influence of preparation parameters,
    J. Phys. Chem. B 109, 22167-22174 (2005).
  22. O. Durupthy, M. Jaber, N. Steunou, J. Maquet, G. T. Chandrappa, and J. Livage
    Vanadium oxide foams: An insight into the structure of the vanadium oxide walls,
    Chem. Mater. 17, 6395-6402 (2005).;
  23. Renée Siegel, Nicolas Dupré, Michel Quarton, and Jérôme Hirschinger
    51V magic angle spinning NMR in VOPO4 phases,
    Magn. Reson. Chem. 42, 1022-1026 (2004).
  24. R. Michalak and H. A. H. Mohammad
    51V-NMR and 51T1(T) of charge ordering and spin gap in alpha'-NaV2O5,
    Solid State NMR 26, 187-196 (2004).
  25. P. E. Stallworth, X. Guo, E. Tatham, S. G. Greenbaum, M. Arrabito, S. Bodoarado, and N. Penazzi
    A solid-state 51V NMR characterization of vanadium sites in LiCoxNi1-xVO4,
    Solid State Ionics 170, 181-186 (2004).
  26. B. A. Gee and A. Wong
    Vanadium-51 MAS and static NMR studies of the binary V2O5-WO3 system,
    J. Phys. Chem. B 107, 8382-8387 (2003).
  27. O. B. Lapina, A. A. Shubin, D. F. Khabibulin, V. V. Terskikh, P. R. Bodart, and J.-P. Amoureux
    Solid-state 51V NMR for characterization of vanadium-containing systems,
    Catal. Today 78, 91-104 (2003).
  28. U. G. Nielsen, H. J. Jakobsen, and J. Skibsted
    Small 51V chemical shift anisotropy for LaVO4 from MQMAS and MAS NMR spectroscopy,
    Solid State NMR 23, 107-115 (2003).
  29. B. Sulikowski, Z. Olejniczak, E. Wloch, J. Rakoczy, R. X. Valenzuela, and V. Cortés Corberán
    Oxidative dehydrogenation of isobutane on MCM-41 mesoporous molecular sieves,
    Appl. Catal. A 232, 189-202 (2002).
  30. U. G. Nielsen, A. Boisen, M. Brorson, C. J. H. Jacobsen, H. J. Jakobsen, and J. Skibsted
    Aluminum orthovanadate (AlVO4): Synthesis and characterization by 27Al and 51V MAS and MQMAS NMR spectroscopy,
    Inorg. Chem. 41, 6432-6439 (2002).
  31. C. J. Fontenot, J. W. Wiench, G. L. Schrader, and M. Pruski
    17O MAS and 3QMAS NMR investigation of crystalline V2O5 and layered V2O5 nH2O gels,
    J. Am. Chem. Soc. 124, 8435-8444 (2002).
  32. N. Kim and C. P. Grey
    Probing oxygen motion in disordered anionic conductors with 17O and 51V MAS NMR spectroscopy,
    Science 297, 1317-1320 (2002).
  33. U. G. Nielsen, J. Skibsted, and H. J. Jakobsen
    ß-VO2 - a V(IV) or a mixed-valence V(III)-V(V) oxide - studied by 51V MAS NMR spectroscopy,
    Chem. Phys. Lett. 356, 73-78 (2002).
  34. Becky Gee
    Homonuclear vanadium-51 dipolar couplings in inorganic solids obtained via Hahn spin echo decay NMR spectroscopy,
    Solid State NMR 19, 73-86 (2001).
  35. J. Spengler, F. Anderle, E. Bosch, R. K. Grasselli, B. Pillep, P. Behrens, O. B. Lapina, A. A. Shubin, H.-J. Eberle, and H. Knözinger
    Antimony oxide-modified vanadia-based catalysts -- Physical characterization and catalytic properties,
    J. Phys. Chem. B 105, 10772-10783 (2001).
  36. R. D. Gougeon, E. B. Brouwer, P. R. Bodart, L. Delmotte, C. Marichal, J.-M. Chézeau, and R. K. Harris
    Solid-state NMR studies of the as-synthesized AlPO4-5/TPAF microporous aluminophosphate,
    J. Phys. Chem. B 105, 12249-12256 (2001).

Related bibliography

  1. Jim Clark: Vanadium
  2. Dieter Rehder
    Vanadium NMR of organovanadium complexes,
    Coord. Chem. Rev. 252, 2209-2223 (2008).
  3. Ashok K. Kakkar and Muhammad S. Khan
    Vanadium 1990,
    Coord. Chem. Rev. 146, 203-210 (1995).


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