Rhenium-185 and rhenium-187 NMR




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Isotope Spin Natural
abundance(%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
Re-185 5/2 37.07 218.0 0.13 4.93E-2 -22.513 KReO4
Re-187 5/2 62.93 207.0 0.13 8.62E-2 -22.744

Solid-state rhenium NMR references

  1. C. M. Widdifield, A. D. Bain, and D. L. Bryce
    Definitive solid-state 185/187Re NMR spectral evidence for and analysis of the origin of high-order quadrupole-induced effects for I = 5/2,
    Phys. Chem. Chem. Phys. 13, 12413-12420 (2011).
    Abstract
     
  2. R. W. Schurko, S. Wi, and L. Frydman
    Dynamic effects on the powder line shapes of half-integer quadrupolar nuclei: a solid-state NMR study of XO4- groups,
    J. Phys. Chem. A 106, 51-62 (2002).
    lucio.frydman@weizmann.ac.il
     
  3. O. Vyaselev, K. Kobayashi, K. Arai, J. Yamazaki, K. Kodama, M. Takigawa, M. Hanawa, and Z. Hiroi
    Cd and Re NMR/NQR in pyrochlore compound Cd2Re2O7,
    J. Phys. Chem. Solids 63, 1031-1034 (2002).
    oleg@issp.u-tokyo.ac.jp (O. Vyaselev)
     
  4. J. A. Davies and S. Dutremez
    Solid state NMR studies of d-block and p-block metal nuclei: applications to organometallic and coordination chemistry,
    Coord. Chem. Rev. 114, 201-247 (1992).
     
  5. C. Dimitropoulos, M. Maglione, and F. Borsa
    Nuclear magnetic and quadrupole resonance in metallic powders in the presence of strong quadrupole interaction: Rhenium metal,
    Phys. Rev. B 37, 3159-3163 (1988).
     

Related bibliography

  1. Josť C. Vites and Mary M. Lynam
    Rhenium 1993,
    Coord. Chem. Rev. 146, A207-A224 (1995).
     
 

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