Magnesium-25 NMR

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Isotope Spin Natural
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
Mg-25 5/2 10.13 19.94 2.67E-3 2.71E-4 6.1195 MgCl2
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Solid-state magnesium NMR references

  1. Jair C. C. Freitas and Mark E. Smith
    Recent advances in solid-state 25Mg NMR spectroscopy,
    Annu. Rep. Nucl. Magn. Reson. Spectrosc. 75, 25-114 (2012).
  2. Jianfeng Zhu and Yining Huang
    A natural abundance solid-state 25Mg NMR study of layered magnesium phosphates,
    Can. J. Chem. 89, 803-813 (2011).
  3. Jair C. C. Freitas, Alan Wong, and Mark E. Smith
    Solid-state natural abundance 25Mg NMR studies of Na2MgEDTA·4H2O – a possible new reference compound for 25Mg NMR spectroscopy,
    Magn. Reson. Chem. 47, 9-15 (2009).
  4. Michael C. Davis, William J. Brouwer, David J. Wesolowski, Lawrence M. Anovitz, Andrew S. Liptonc, and Karl T. Mueller
    Magnesium silicate dissolution investigated by 29Si MAS, 1H–29Si CPMAS, 25Mg QCPMG, and 1H–25Mg CP QCPMG NMR,
    Phys. Chem. Chem. Phys. 11, 7013-7021 (2009).
  5. T. J. Bastowa and S. Celotto
    25Mg NMR site analysis in metals and intermetallics,
    Solid State Nucl. Magn. Reson. 35, 217-222 (2009).
  6. C. M. Widdifield and D. L. Bryce
    Crystallographic structure refinement with quadrupolar nuclei: a combined solid-state NMR and GIPAW DFT example using MgBr2,
    Phys. Chem. Chem. Phys. 11, 7120-7122 (2009).
  7. Zhehong Gan, Peter L. Gor’kov, William W. Brey, Paul J. Sideris, and Clare P. Grey
    Enhancing MQMAS of low-γ nuclei by using a high B1 field balanced probe circuit,
    J. Magn. Reson. 200, 2-5 (2009).
  8. J. F. Zhu, Z. Lin, Z. M. Yan, and Y. N. Huang
    91Zr and 25Mg solid-state NMR characterization of the local environments of the metal centers in microporous materials,
    Chem. Phys. Lett. 461, 260-265 (2008).
  9. K. Shimoda, T. Nemoto, and K. Saito
    Local structure of magnesium in silicate glasses: A 25Mg 3QMAS NMR study,
    J. Phys. Chem. B 112, 6747-6752 (2008).
  10. K. Shimoda, Y. Tobu, M. Hatakeyama, T. Nemoto, and K. Saito
    Structural investigation of Mg local environments in silicate glasses by ultra-high field 25Mg 3QMAS NMR spectroscopy,
    Am. Mineral. 92, 695-698 (2007).
  11. A. Wong, R. Ida, X. Mo, Z. H. Gan, J. Poh, and G. Wu
    Solid-state 25Mg NMR spectroscopic and computational studies of organic compounds. Square-pyramidal magnesium(II) ions in aqua(magnesium) phthalocyanine and chlorophyll a,
    J. Phys. Chem. A 110, 10084-10090 (2006).
  12. N. G. Dowell, S. E. Ashbrook, and S. Wimperis
    Satellite-transition MAS NMR of low-gamma nuclei at natural abundance: sensitivity, practical implementation, and application to 39K (I = 3/2) and 25Mg (I = 5/2),
    J. Phys. Chem. B 108, 13292-13299 (2004).
  13. A. S. Lipton, R. W. Heck, J. A. Sears, and P. D. Ellis
    Low temperature solid-state NMR experiments of half-integer quadrupolar nuclides: caveats and data analysis,
    J. Magn. Reson. 168, 66-74 (2004).
  14. M. D. Glinchuk, A. N. Morozovskaya, A. M. Slipenyuk, and I. P. Bykov
    Peculiarities of the radiospectroscopy line shape in nanomaterials,
    Appl. Magn. Reson. 24, 333-342 (2003).
  15. Ivan Hung and Robert W. Schurko
    Solid-state 25Mg QCPMG NMR of bis(cyclopentadienyl)magnesium,
    Solid State NMR 24, 78-93 (2003).
  16. G. Wu, A. Wong, and S. N. Wang
    Solid-state 25Mg NMR, X-ray crystallographic, and quantum mechanical study of bis(pyridine)-(5,10,15,20-tetraphenylporphyrinato)magnesium(II),
    Can. J. Chem. 81, 275-283 (2003).
  17. T. J. Bastow
    Electric field gradients at the M-site in MCO3: M = Mg, Ca, Sr and Ba,
    Chem. Phys. Lett. 354, 156-159 (2002).
  18. T. J. Bastow
    25Mg NMR determination of Knight shift, spin-lattice relaxation and electric field gradient in MgB2,
    Solid State Commun. 124, 269-273 (2002).
  19. S. Kroeker, P. S. Neuhoff, and J. F. Stebbins
    Enhanced resolution and quantitation from ultrahigh field NMR spectroscopy of glasses,
    J. Non-Cryst. Solids 293-295, 440-445 (2001).
  20. Scott Kroeker and Jonathan F. Stebbins
    Magnesium coordination environments in glasses and minerals: New insight from high-field magnesium-25 MAS NMR,
    Amer. Mineral. 85, 1459-1464 (2000).
  21. F. H. Larsen, J. Skibsted, H. J. Jakobsen, and N. C. Nielsen
    Solid-state QCPMG NMR of low-gamma quadrupolar metal nuclei in natural abundance,
    J. Am. Chem. Soc. 122, 7080-7086 (2000).
  22. S. Sham and G. Wu
    Solid-state 25Mg NMR study of inner-sphere Mg2+ binding complexes,
    Inorg. Chem. 39, 4-5 (2000).

Related bibliography

  1. T. Iijima and M. Mizuno
    Effect of molecular dynamics and modulated structure on 2H NMR spectrum studied in [Mg(H2O)6][SiF6],
    Chem. Phys. Lett. 380, 736-741 (2003).

More solid-state Mg-25 NMR references.



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