Lanthanum-139 NMR




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Isotope Spin Natural
abundance(%)
Quadrupole moment
(10-30m2)
Relative
sensitivity
Absolute
sensitivity
NMR frequency (MHz)
at a field of 2.3488T
Reference
sample
La-138 5 0.089 45.0 9.19E-2 8.18E-5 -13.193 LaCl3
La-139 7/2 99.91 20.0 5.92E-2 5.91E-2 -14.126

Solid-state lanthanum NMR references

  1. B. Nowak, O. Zogal, Z. Henkie, M. B. Maple
    Multiple quadrupolar spin echoes in the La-filled skutterudite LaOs4As12,
    Solid State Nucl. Magn. Reson. 36, 209-211 (2009).
    Abstract
     
  2. A. L. Rollet, S. Godier, and C. Bessada
    High temperature NMR study of the local structure of molten LaF3-AF (A = Li, Na, K and Rb) mixtures,
    Phys. Chem. Chem. Phys. 10, 3222-3228 (2008).
     
  3. A. Y. H. Lo, V. Sudarsan, S. Sivakumar, F. van-Veggel, and R. W. Schurko
    Multinuclear solid-state NMR spectroscopy of doped lanthanum fluoride nanoparticles,
    J. Am. Chem. Soc. 129, 4687-4700 (2007).
    fvv@uvic.ca, rschurko@uwindsor.ca
     
  4. Hiyam Hamaed, Andy Y. H. Lo, David S. Lee, William J. Evans, and Robert W. Schurko
    Solid-state 139La and 15N NMR spectroscopy of lanthanum-containing metallocenes,
    J. Am. Chem. Soc. 128, 12638-12639 (2006).
    Abstract
     
  5. S. A. Lekomtsev, K. N. Mikhalev, A. Y. Yakubovskii, and A. R. Kaul
    Features of low-frequency spin dynamics in manganite LaMnO3 according to 139La NMR data,
    J. Exp. Theo. Phys. 102, 671-676 (2006).
    mikhalev@imp.uran.ru
     
  6. T. J. Bastow, T. Mathews, and J. R. Sellar
    69,71Ga and 139La NMR characterisation of LaGaO3 and La1-xSrxGa1-xMgxO3-x,
    Solid State Ionics 175, 129-133 (2004).
    tim.bastow@csiro.au
     
  7. J. Bartolomé, M. D. Kuz'min, Cz. Kapusta, P. C. Riedi, M. Ellouze, and Ph. l'Héritier
    Hydrogen-induced reduction of electric field gradient in La2Fe14BHx studied by NMR on 139La,
    Solid State Commun. 129, 331-334 (2004).
    kuzmin@unizar.es
     
  8. P. K. Madhu, O. G. Johannessen, K. J. Pike, R. Dupree, M. E. Smith, and M. H. Levitt
    Application of amplitude-modulated radiofrequency fields to the magic-angle spinning NMR of spin-7/2 nuclei,
    J. Magn. Reson. 163, 310-317 (2003).
    mhl@soton.ac.uk
     
  9. K. N. Mikhalev, S. A. Lekomtsev, A. P. Gerashchenko, A. Yu. Yakubovskii, and A. R. Kaul
    Short-range magnetic order in LaMn(O1-xFx)3 from 139La and 19F NMR Data,
    JETP Lett. 77, 401-404 (2003).
     
  10. D. J. Aurentz, F. G. Vogt, K. T. Mueller, and A. J. Benesi
    Multiple-rotor-cycle QPASS pulse sequences: Separation of quadrupolar spinning sidebands with an application to 139La NMR,
    J. Magn. Reson. 138, 320-325 (1999).
     
  11. G. Papavassiliou, M. Fardis, F. Milia, M. Pissas, G. Kallias, D. Niarchos, C. Dimitropoulos, and P. Scherrer
    NMR in manganese perovskites: Detection of spatially varying electron states in domain walls,
    Phys. Rev. B 58, 12237-12241 (1998).
     
  12. T. Yaita, D. Ito, and S. Tachimori
    139La NMR relaxation and chemical shift studies in the aqueous nitrate and chloride solutions,
    J. Phys. Chem. B 102, 3886-3891 (1998).
     
  13. T. J. Bastow
    139La NMR characterization of La2O3 and La1-xSrxMO3 where M = Cr, Mn or Co,
    Solid State NMR 3, 17-22 (1994).
     
  14. B. Herreros, P. P. Man, J.-M. Manoli, and J. Fraissard
    Solid-state 139La NMR investigation of lanthanum-exchanged Y zeolites (PDF article, 250 Kb),
    J. Chem. Soc., Chem. Commun. 464-466 (1992).
     

Related bibliography

  1. W. L. Huang, M. Schopfer, C. Zhang, R. C. Howell, L. Todaro, B. A. Gee, L. C. Francesconi, and T. Polenova
    31P magic angle spinning NMR spectroscopy of paramagnetic rare-earth-substituted Keggin and Wells-Dawson solids,
    J. Am. Chem. Soc. 130, 481-490 (2008).
     

More solid-state La-139 NMR references.


 

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