Cesium-133 NMR

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Isotope Spin Natural
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
Cs-133 7/2 100 -0.343 4.74E-2 4.74E-2 -13.117 CsNO3
. . . . . . . .

Solid-state cesium NMR references

  1. Thorsten Goebel, Alim Ormeci, Oliver Pecher, and Frank Haarmann
    The silicides M4Si4 with M = Na, K, Rb, Cs, and Ba2Si4 – NMR spectroscopy and quantum mechanical calculations,
    Z. Anorg. Allg. Chem. 638, 1437-1445 (2012).
  2. C. Martineau, V. K. Michaelis, S. Schuller, and S. Kroeker
    Liquid-liquid phase separation in model nuclear waste glasses: A solid-state double resonance NMR study,
    Chem. Mater. 22, 4896-4903 (2010).
  3. S. Kroeker, C. S. Higman, V. K. Michaelis, N. B. Svenda, and S. Schuller
    Precipitation of mixed-alkali molybdates during HLW vitrification,
    Mater. Res. Soc. Symp. Proc. 1265, AA03-03-09 (2010).
  4. V. K. Michaelis and S. Kroeker
    Caesium volatilisation in borosilicate glasses: a multinuclear magnetic resonance study,
    Phys. Chem. Glasses 50, 249-252 (2009).
  5. Catherine J. Reinhold, Paul A. Anderson, Peter P. Edwards, Victor V. Terskikh, Christopher I. Ratcliffe, and John A. Ripmeester
    Cs NMR and ESR studies of cesium-loaded LiX and LiA zeolites,
    J. Phys. Chem. C 112, 17796-17803 (2008).
  6. Vladimir K. Michaelis, Pedro M. Aguiar, and Scott Kroeker
    Probing alkali coordination environments in alkali borate glasses by multinuclear magnetic resonance,
    J. Non-Cryst. Solids 353, 2582-2590 (2007).
  7. K. R. Whittle, G. R. Lumpkin, and S. E. Ashbrook
    Neutron diffraction and MAS NMR of Cesium Tungstate defect pyrochlores,
    J. Solid State Chem. 179, 512-521 (2006).
  8. T. Gullion and A. J. Vega
    Measuring heteronuclear dipolar couplings for I=1/2, S > 1/2 spin pairs by REDOR and REAPDOR NMR,
    Progr. Nucl. Magn. Reson. Spectrosc. 47, 123-136 (2005).
    terry.gullion@mail.wvu.edu; lexvega@chem.udel.edu
  9. R. B. Ejeckam and B. L. Sherriff
    A 133Cs, 29Si, and 27Al MAS NMR spectroscopic study of Cs adsorption by clay minerals: Implications for the disposal of nuclear wastes,
    Can. Mineralog. 43, 1131-1140 (2005).
  10. J. Mon, Y. J. Deng, M. Flury, J. B. Harsh
    Cesium incorporation and diffusion in cancrinite, sodalite, zeolite, and allophane,
    Microporous Mesoporous Mater. 86, 277-286 (2005).
  11. E. J. Lima, I.A. Ibarra, M. A. Vera, V. H. Lara, P. Bosch, and S. Bulbulian
    I. Cesium leaching in CsA and CsX zeolites,
    J. Phys. Chem. B 108, 12103-12110 (2004).
  12. C. A. Click, R. K. Brow, and T. M. Alam
    Properties and structure of cesium phosphate glasses,
    J. Non-Cryst. Solids 311, 294-303 (2003).
  13. Anil Kumar, K. V. Ramanathan, T. S. Mahesh, Neeraj Sinha, and K. V. R. Murali
    Developments in quantum information processing by nuclear magnetic resonance: Use of quadrupolar and dipolar couplings,
    Pramana – J. Phys. 59, 243-254 (2002).
  14. V. Luca, J. V. Hanna, M. E. Smith, M. James, D. R. G. Mitchell, J. R. Bartlett
    Nb-substitution and Cs+ ion-exchange in the titanosilicate sitinakite,
    Microporous Mesoporous Mater. 55, 1-13 (2002).
  15. M. Hunger, U. Schenk, and A. Buchholz
    Mobility of cations and guest compounds in cesium-exchanged and impregnated zeolites Y and X investigated by high-temperature MAS NMR spectroscopy,
    J. Phys. Chem. B 104, 12230-12236 (2000).
  16. J. Skibsted, T. Vosegaard, H. Bildsoe, and H. J. Jakobsen
    133Cs chemical shielding anisotropies and quadrupole couplings from MAS NMR of cesium salts,
    J. Phys. Chem. 100, 14872-14881 (1996).
  17. W. P. Power, S. Mooibroek, R. E. Wasylishen, and T. S. Cameron
    Cesium-133 single-crystal NMR study of cesium chromate,
    J. Phys. Chem. 98, 1552-1560 (1994).
  18. W. P. Power, R. E. Wasylishen, S. Mooibroek, B. A. Pettitt, and W. Danchura
    Simulation of NMR powder line shapes of quadrupolar nuclei with half-integer spin at low-symmetry sites,
    J. Phys. Chem. 94, 591-598 (1990).

Related bibliography

  1. M. Gutjahr, R. Böttcher, and A. Pöppl
    133Cesium HYSCORE investigation of the di-tert-butyl nitroxide--Cs+ adsorption complex in CsNaY zeolite,
    J. Phys. Chem. 107, 13117-13122 (2003).

More solid-state Cs-133 NMR references.



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