Bromine-79 and bromine-81 NMR

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Isotope Spin Natural
Quadrupole moment
NMR frequency (MHz)
at a field of 2.3488T
Br-79 3/2 50.54 31.3 7.86E-2 3.97E-2 -25.053 NaBr
Br-81 3/2 49.46 26.2 9.85E-2 4.87E-2 -27.006

Solid-state bromine NMR references

  1. C. M. Widdifield and D. L. Bryce
    Solid-state 79/81Br NMR and gauge-including projector-augmented wave study of structure, symmetry, and hydration state in alkaline earth metal bromides,
    J. Phys. Chem. A 114, 2102-2116 (2010).
  2. C. M. Widdifield and D. L. Bryce
    Crystallographic structure refinement with quadrupolar nuclei: a combined solid-state NMR and GIPAW DFT example using MgBr2,
    Phys. Chem. Chem. Phys. 11, 7120-7122 (2009).
  3. C. M. Widdifield, R. P. Chapman, and D. L. Bryce
    Chlorine, bromine, and iodine solid-state NMR spectroscopy,
    Annu. Rep. Nucl. Magn. Reson. Spectrosc. 66, 195-326 (2009).
  4. R. P. Chapman, C. M. Widdifield, and D. L. Bryce
    Solid-state NMR of quadrupolar halogen nuclei,
    Prog. Nucl. Magn. Reson. Spectrosc. 55, 215-237 (2009).
  5. R. P. Chapman and D. L. Bryce
    Application of multinuclear magnetic resonance and gauge-including projector-augmented wave calculations to the study of solid group 13 chlorides,
    Phys. Chem. Chem. Phys. 11, 6987-6998 (2009).
  6. J. Persons and G. S. Harbison
    Slow turning reveals enormous quadrupolar interactions (STREAQI),
    J. Magn. Reson. 186, 347-351 (2007).
  7. D. L. Bryce and G. D. Sward
    Solid-state NMR spectroscopy of the quadrupolar halogens: chlorine-35/37, bromine-79/81, and iodine-127,
    Magn. Reson. Chem. 44, 409-450 (2006).
  8. D. L. Bryce, G. M. Bernard, M. Gee, M. D. Lumsden, K. Eichele, and R. Wasylishen
    Practical aspects of modern routine solid-state multinuclear magnetic resonance spectroscopy: one-dimensional experiments,
    Can. J. Anal. Sci. Spectrosc. 46, 46-82 (2001).
  9. S. Hayashi and K. Hayamizu
    Effect of spinning on chemical shifts in magic-angle-spinning nuclear magnetic resonance,
    J. Chem. Phys. 92, 2818-2827 (1990).
  10. P. Brenni, D. Brinkmann, H. Huber, M. Mali, J. Roos, and H. Arend
    Detection of a second Br site in K2Pt(CN)4 Br0.3 3.2H2O (KCP) by 81Br and 39K NMR,
    Solid State Commun. 47, 415-418 (1983).
  11. J. S. Frye and G. E. Maciel
    Setting the magic angle using a quadrupolar nuclide,
    J. Magn. Reson. 48, 125-131 (1982).

Related bibliography

  1. B. Nagasaka, S. Takeda, and N. Nakamura
    Residual dipolar splittings in 13C CP/MAS NMR spectra due to quadrupolar halogen nuclei in uracil halides,
    Chem. Phys. Lett. 222, 486-492 (1994).

More solid-state Br-79/81 NMR references.



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